Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent
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منابع مشابه
Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent
Transition metal reagents and catalysts are generally effective to cleave all three bonds (one σ and two π) in a triple bond despite its high bonding energy. Recently, chemistry of single-bond cleavage by using main-group element compounds is rapidly being developed in the absence of transition metals. However, the cleavage of a triple bond using non-transition-metal compounds is less explored....
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2014
ISSN: 2041-1723
DOI: 10.1038/ncomms5245